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What a peptide certificate of analysis should actually include

Jonathan Cole · · Quality Compliance

A certificate of analysis is a lab's statement that a specific lot met a written specification. Anything that doesn't name the lot, the tests and the results is not a CoA. Here is what to expect on a peptide CoA from a supplier who intends to stand behind it.

Identifiers

  • Product name and sequence or CAS reference
  • Lot or batch number matching the vial label
  • Manufacture date and retest or expiry date
  • Issuing lab and a signature or approval

Purity

Purity by analytical HPLC, reported as a percentage with the method named (column, gradient, detection wavelength). A specification of at least 99% is standard for pharmacy-grade material. Ask to see the chromatogram; a single clean peak with small, identified impurities is what you want.

Identity

Mass spectrometry (LC-MS or MALDI) confirming the observed mass matches the theoretical mass of the sequence. Purity without identity means a very pure sample of something; identity is what tells you it's the right something.

Content

Net peptide content on bulk API, because lyophilized peptides carry water and counter-ion (acetate or TFA). A 10 mg vial that is 85% net peptide contains 8.5 mg of peptide. Pharmacies need this number to compound accurately.

Safety tests on injectable-grade vials

  • Bacterial endotoxin (LAL), typically reported in EU/mg
  • Sterility per USP <71>
  • Water content by Karl Fischer on bulk
  • Residual solvents where relevant

What a marketing sheet looks like

No lot number. "Purity: 99%+" with no method. The same PDF for every batch. A logo but no lab. If your current supplier's documents match that description, you are carrying the risk they should be carrying.

Every lot we ship carries a CoA built to this list. Request a sample.